Hi,
Your tank holds somewhere in the region of 240 litres (provided you don't have huge amounts of rockwork or gravel), so 10 neons and a Leopard plec (assuming it's a small one) after a week of running empty should not send ammonia levels through the roof, provided you are very mean with the food. I'm also assuming you have the correct level of filtration for the size of tank.
Personally, if the fish are swimming about quite happily at the moment with their fins erect, and are interested in food, I wouldn't panic and take them back - the extra stress of moving them again could doom them quicker than a partially mature filter. However, if you see any fins clamped down against the body, loss of colouration or lack of appetite, back they go!
Hope that reassures you a bit - "New tank syndrome", as it's called when you overload a tank without maturing it properly, is still far too common, but each system is different and the fish themselves (along with regular testing of ammonia, nitrite and nitrate levels) will soon let you know if there's a problem!
There are several species of Suckermouth Catfish which get called Leopard Plec, but the one that springs to mind has the latin name Pseudacanthicus leopardus, and is absolutely stunning!